Volek (Czech feminine: Volková) is a surname. Notable people with the surname include:
- Billy Volek (born 1976), American football player
- David Volek (born 1966), Czech ice hockey player
- Jaroslav Volek (1923–1989), Czech musicologist
- Zdeněk Volek (born 1985), Czech footballer
- Fictional characters
- Nika Volek, a minor character on the American television series Prison Break