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Germanite

Germanite is a rare copper iron germanium sulfide mineral, Cu26Fe4Ge4S32. It was first discovered in 1922, and named for its germanium content. It is only a minor source of this important semiconductor element, which is mainly derived from the processing of the zinc sulfide mineral sphalerite. Germanite contains gallium, zinc, molybdenum, arsenic, and vanadium as impurities.

Last revised
Jun 3, 2026
Read time
≈ 1 min
Length
248 w
Citations
11
Source
Germanite
Germanite, probably from the Tsumeb Mine, Oshikoto Region, Namibia.
General
CategorySulfide mineral
FormulaCu26Ge4Fe4S321
IMA symbolGer2
Strunz classification2.CB.30
Dana classification2.9.4.2
Crystal systemIsometric
Crystal classHextetrahedral (43m)
H-M symbol: (4 3m)
Space groupP43n
Identification
ColorReddish grey tarnishing to dark brown
Crystal habitUsually massive; rarely as minute cubic crystals
CleavageNone
TenacityBrittle
Mohs scale hardness4
LusterMetallic
StreakDark grey to black
DiaphaneityOpaque
Specific gravity4.4 to 4.6
Other characteristicsCell data: a = 10.585 Å Z = 13
References45

Germanite is a rare copper iron germanium sulfide mineral, Cu26Fe4Ge4S32. It was first discovered in 1922, and named for its germanium content.3 It is only a minor source of this important semiconductor element, which is mainly derived from the processing of the zinc sulfide mineral sphalerite.6 Germanite contains gallium, zinc, molybdenum, arsenic, and vanadium as impurities.3

Its type locality is the Tsumeb Mine in Namibia where it occurs in a hydrothermal polymetallic ore deposit in dolomite in association with renierite, pyrite, tennantite, enargite, galena, sphalerite, digenite, bornite and chalcopyrite.5 It has also been reported from Argentina, Armenia, Bulgaria, Cuba, Democratic Republic of Congo (Zaire), Finland, France, Greece, Japan, Republic of Congo (Brazzaville), Russia and the United States.3

X-Ray Powder Diffraction7
d spacing 3.05 2.65 1.87 1.60 1.32 1.21 1.08 1.02
relative intensity 10 1 7 4 1 2 2 1
References

References

  1. American Mineralogist (1984) 69:943-947
  2. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  3. http://www.mindat.org/min-1681.html Mindat.org
  4. http://webmineral.com/data/Germanite.shtml Webmineral
  5. http://rruff.geo.arizona.edu/doclib/hom/germanite.pdf Handbook of Mineralogy
  6. U.S. Geological Survey (2008), "Germanium—Statistics and Information", U.S. Geological Survey, Mineral Commodity Summaries https://minerals.usgs.gov/minerals/pubs/commodity/germanium/ Archived 2008-09-16 at the Wayback Machine
  7. Dana's New Mineralogy, 8th edition, Gaines et al., Wiley