Article · Wikipedia archive · Last revised Aug 7, 2026

Rubidium bromide

Rubidium bromide is an inorganic compound with the chemical formula RbBr. It is a salt of hydrogen bromide. It consists of bromide anions Br− and rubidium cations Rb+. It has a NaCl crystal structure, with a lattice constant of 685 picometres.

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Aug 7, 2026
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Source
Rubidium bromide
Rubidium bromide
Rubidium bromide source ↗
Names
IUPAC name
Rubidium bromide
Other names
Rubidium(I) bromide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.029.238
UNII
  • InChI=1S/BrH.Rb/h1H;/q;+1/p-1 checkY
    Key: JAAGVIUFBAHDMA-UHFFFAOYSA-M checkY
  • InChI=1/BrH.Rb/h1H;/q;+1/p-1
    Key: JAAGVIUFBAHDMA-REWHXWOFAB
  • [Rb+].[Br-]
Properties1
RbBr
Molar mass 165.372 g/mol
Appearance white crystalline solid
Density 3.35 g/cm3
Melting point 682 °C (1,260 °F; 955 K)
Boiling point 1,340 °C (2,440 °F; 1,610 K)
47.26 g/100 mL (0.5°C)
53.69 g/100 mL (25°C)
67.24 g/100 mL (113.5°C)
−56.4·10−6 cm3/mol
Hazards
Flash point Non-flammable
Thermochemistry
Enthalpy of fusion fHfus)
15.50 kJ/mol1
Related compounds
Other anions
Rubidium fluoride
Rubidium chloride
Rubidium iodide
Rubidium astatide
Other cations
Lithium bromide
Sodium bromide
Potassium bromide
Caesium bromide
Francium bromide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Rubidium bromide is an inorganic compound with the chemical formula RbBr. It is a salt of hydrogen bromide. It consists of bromide anions Br and rubidium cations Rb+. It has a NaCl crystal structure, with a lattice constant of 685 picometres.2

Preparation

There are several methods for synthesising rubidium bromide. One involves reacting rubidium hydroxide with hydrobromic acid:

RbOH + HBr → RbBr + H2O

Another method is to neutralize rubidium carbonate with hydrobromic acid:

Rb2CO3 + 2 HBr → 2 RbBr + H2O + CO2
References

References

  1. Perry, Dale L. (2016-04-19). Handbook of Inorganic Compounds. CRC Press. p. 348. ISBN 978-1-4398-1462-8.
  2. G. Chern; J. G. Skofronick; W. P. Brug; S. A. Safron (1989). "Surface phonon modes of the RbBr(001) crystal surface by inelastic He-atom scattering". Phys. Rev. B. 39 (17): 12838–12844. Bibcode:1989PhRvB..3912838C. doi:10.1103/PhysRevB.39.12838. PMID 9948158.