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Absorptance

In the study of heat transfer, absorptance of the surface of a material is its effectiveness in absorbing radiant energy. It is the ratio of the absorbed to the incident radiant power.

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In the study of heat transfer, absorptance of the surface of a material is its effectiveness in absorbing radiant energy. It is the ratio of the absorbed to the incident radiant power.1

Mathematical definitions

Hemispherical absorptance

Hemispherical absorptance of a surface, denoted A is defined as2

A = Φ e a Φ e i , {\displaystyle A=\mathrm {\frac {\Phi _{e}^{a}}{\Phi _{e}^{i}}} ,}

where

  • Φ e a {\displaystyle \mathrm {\Phi _{e}^{a}} } is the radiant flux absorbed by that surface;
  • Φ e i {\displaystyle \mathrm {\Phi _{e}^{i}} } is the radiant flux received by that surface.

Spectral hemispherical absorptance

Spectral hemispherical absorptance in frequency and spectral hemispherical absorptance in wavelength of a surface, denoted Aν and Aλ respectively, are defined as2

A ν = Φ e , ν a Φ e , ν i , A λ = Φ e , λ a Φ e , λ i , {\displaystyle {\begin{aligned}A_{\nu }&=\mathrm {\frac {\Phi _{e,\nu }^{a}}{\Phi _{e,\nu }^{i}}} ,\\A_{\lambda }&=\mathrm {\frac {\Phi _{e,\lambda }^{a}}{\Phi _{e,\lambda }^{i}}} ,\end{aligned}}}

where

  • Φ e , ν a {\displaystyle \mathrm {\Phi _{e,\nu }^{a}} } is the spectral radiant flux in frequency absorbed by that surface;
  • Φ e , ν i {\displaystyle \mathrm {\Phi _{e,\nu }^{i}} } is the spectral radiant flux in frequency received by that surface;
  • Φ e , λ a {\displaystyle \mathrm {\Phi _{e,\lambda }^{a}} } is the spectral radiant flux in wavelength absorbed by that surface;
  • Φ e , λ i {\displaystyle \mathrm {\Phi _{e,\lambda }^{i}} } is the spectral radiant flux in wavelength received by that surface.

Directional absorptance

Directional absorptance of a surface, denoted AΩ, is defined as2

A Ω = L e , Ω a L e , Ω i , {\displaystyle A_{\Omega }={\frac {L_{\mathrm {\mathrm {e} ,\Omega } }^{\mathrm {a} }}{L_{\mathrm {e} ,\Omega }^{\mathrm {i} }}},}

where

  • L e , Ω a {\displaystyle L\mathrm {_{e,\Omega }^{a}} } is the radiance absorbed by that surface;
  • L e , Ω i {\displaystyle L\mathrm {_{e,\Omega }^{i}} } is the radiance received by that surface.

Spectral directional absorptance

Spectral directional absorptance in frequency and spectral directional absorptance in wavelength of a surface, denoted Aν,Ω and Aλ,Ω respectively, are defined as2

A ν , Ω = L e , Ω , ν a L e , Ω , ν i , A λ , Ω = L e , Ω , λ a L e , Ω , λ i , {\displaystyle {\begin{aligned}A_{\nu ,\Omega }&={\frac {L\mathrm {_{e,\Omega ,\nu }^{a}} }{L\mathrm {_{e,\Omega ,\nu }^{i}} }},\\[4pt]A_{\lambda ,\Omega }&={\frac {L\mathrm {_{e,\Omega ,\lambda }^{a}} }{L\mathrm {_{e,\Omega ,\lambda }^{i}} }},\end{aligned}}}

where

  • L e , Ω , ν a {\displaystyle L\mathrm {_{e,\Omega ,\nu }^{a}} } is the spectral radiance in frequency absorbed by that surface;
  • L e , Ω , ν i {\displaystyle L\mathrm {_{e,\Omega ,\nu }^{i}} } is the spectral radiance received by that surface;
  • L e , Ω , λ a {\displaystyle L\mathrm {_{e,\Omega ,\lambda }^{a}} } is the spectral radiance in wavelength absorbed by that surface;
  • L e , Ω , λ i {\displaystyle L\mathrm {_{e,\Omega ,\lambda }^{i}} } is the spectral radiance in wavelength received by that surface.

Other radiometric coefficients

Quantity SI units Notes
Name Sym.
Hemispherical emissivity ε N/a Radiant exitance of a surface, divided by that of a black body at the same temperature as that surface.
Spectral hemispherical emissivity εν
ελ
N/a Spectral exitance of a surface, divided by that of a black body at the same temperature as that surface.
Directional emissivity εΩ N/a Radiance emitted by a surface, divided by that emitted by a black body at the same temperature as that surface.
Spectral directional emissivity εΩ,ν
εΩ,λ
N/a Spectral radiance emitted by a surface, divided by that of a black body at the same temperature as that surface.
Hemispherical absorptance A N/a Radiant flux absorbed by a surface, divided by that received by that surface. This should not be confused with "absorbance".
Spectral hemispherical absorptance Aν
Aλ
N/a Spectral flux absorbed by a surface, divided by that received by that surface. This should not be confused with "spectral absorbance".
Directional absorptance AΩ N/a Radiance absorbed by a surface, divided by the radiance incident onto that surface. This should not be confused with "absorbance".
Spectral directional absorptance AΩ,ν
AΩ,λ
N/a Spectral radiance absorbed by a surface, divided by the spectral radiance incident onto that surface. This should not be confused with "spectral absorbance".
Hemispherical reflectance R N/a Radiant flux reflected by a surface, divided by that received by that surface.
Spectral hemispherical reflectance Rν
Rλ
N/a Spectral flux reflected by a surface, divided by that received by that surface.
Directional reflectance RΩ N/a Radiance reflected by a surface, divided by that received by that surface.
Spectral directional reflectance RΩ,ν
RΩ,λ
N/a Spectral radiance reflected by a surface, divided by that received by that surface.
Hemispherical transmittance T N/a Radiant flux transmitted by a surface, divided by that received by that surface.
Spectral hemispherical transmittance Tν
Tλ
N/a Spectral flux transmitted by a surface, divided by that received by that surface.
Directional transmittance TΩ N/a Radiance transmitted by a surface, divided by that received by that surface.
Spectral directional transmittance TΩ,ν
TΩ,λ
N/a Spectral radiance transmitted by a surface, divided by that received by that surface.
Hemispherical attenuation coefficient μ m−1 Radiant flux absorbed and scattered by a volume per unit length, divided by that received by that volume.
Spectral hemispherical attenuation coefficient μν
μλ
m−1 Spectral radiant flux absorbed and scattered by a volume per unit length, divided by that received by that volume.
Directional attenuation coefficient μΩ m−1 Radiance absorbed and scattered by a volume per unit length, divided by that received by that volume.
Spectral directional attenuation coefficient μΩ,ν
μΩ,λ
m−1 Spectral radiance absorbed and scattered by a volume per unit length, divided by that received by that volume.
References

References

  1. IUPAC, Compendium of Chemical Terminology, 5th ed. (the "Gold Book") (2025). Online version: (2006–) "Absorptance". doi:10.1351/goldbook.A00035
  2. "Thermal insulation — Heat transfer by radiation — Physical quantities and definitions". ISO 9288:1989. ISO catalogue. 1989. Retrieved 2015-03-15.